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Q.

Correct increasing order of pKb values    in the above compounds is

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a

IV, III, II, I

b

IV, II, I, III

c

I, II, III, IV

d

II, I, III, IV

answer is A.

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Detailed Solution

A) I, II, III are aryl amines. In these amines the lone pair is involved in resonance. They are less basic ;As the number of benzene rings increases delocalization of lone pair increases, basic strength decreases.B) IV is a aryl alkyl amine in which the lone pair is localized. It is more basic; ∴ basic strength of IV > III > II > I;pkb of IV < III < II < I.
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