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Questions  

Correct match to replace -Cl group with -OH group in the following 

I) 
A) NaOH,368K/H+
II) 
B) NaOH, 443/H+
III) 
C) NaOH, 623K, 320 atm/H+
IV) 
D) Warm H2O

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a
b
c
d

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detailed solution

Correct option is C

Intermediate is carbanion negative charge delocalizes at ortho & para position. ∴ carbanion is stabilized by EWG −NO2,−CHO....etcCarbanion is destablized by EDG −OCH3,−CH3Greater the number of -NO2 groups at ortho & para position more will be the rate of reactivity towards nucleophilic substitution-NO2 group at meta position has negligible effect. In fact reactivity of nucleophilic substitution
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