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Q.

The correct order of increasing basicity of the given conjugate bases R=CH3 is

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a

RCOO- < HC =C-< R-

b

R-< HC ≡C-

c

RCOO-

d

RCOO-

answer is D.

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Detailed Solution

In carboxylate ion, the negative charge is present on oxygen, a most electronegative element here, thus it is resonance stabilized. HC≡C-: Carbon is sp hybridized so its electronegativity is increased higher relative to nitrogen. N¯H2 : Nitrogen is more electronegative than sp3 hybridized C-atom. From the above discussion, it is clear that the order of the stability of conjugated bases is as RCOO-
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The correct order of increasing basicity of the given conjugate bases R=CH3 is