The correct order of normal boiling points of O2, N2, NH3 and CH4 for whom the values of van der Waals constant ‘a’ are 1.360, 1.390, 4.170 and 2.253 L2 atm mol-2 respectively, is
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a
O2 < N2 < NH3 < CH4
b
O2 < N2 < CH4 < NH3
c
NH3 < CH4 < N2 < O2
d
NH3 < CH4 < O2 < N2
answer is B.
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Detailed Solution
As ‘a’ value increases , attractive interactions increases Hence B.P increases.