Correct order of priorities of various groups according to CIP rules is
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a
–OH > – NH2 > – COOH > – CHO
b
– COOH > – CHO > – OH > – NH2
c
–Br > – OH > – CN > –COOH
d
–NH2 > – NO2 > – CH3 > – C2H5
answer is A.
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Detailed Solution
According to CIP rules, the group in which the directly attached atom has highest atomic number is given the highest priority ;If the directly attached atom is the same then the next atom must be considered ;Each double bonded (or) triple bonded atom is considered as two such (or) three such atoms respectively.∴ – OH > – NH2 > – COOH > –CHO – OH > – NH2 > C, O, O, O > –C, O, O, H