Q.

The correct relationship between the boiling points of very dilute solutions of AlCl3 (t1) and CaCl2 (t2),having the same molar concentration, is

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a

t1 = t2

b

t1 > t2

c

t2 > t1

d

t2 ≥ t1

answer is B.

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Detailed Solution

AlCl3 furnishes more ions than CaCl2 and thus shows higher boiling point.
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The correct relationship between the boiling points of very dilute solutions of AlCl3 (t1) and CaCl2 (t2),having the same molar concentration, is