Q.

Correct sequence of strength of  overlaps is

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a

σp−p > σs−p> σs−s > πp−p

b

σp−p > πp−p> σs−p > σs−s

c

σs−s > σs−p> σp−p > πp−p

d

σp−p > πp−p> σs−s > σs−p

answer is A.

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Detailed Solution

Pi bond is never stronger than a sigma bond. In general P–P > S–P > S–S (overlapping strength). Orbital with directional nature will have more overlapping capacity .
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