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The correct statement about the magnetic properties of [Fe(CN)6]3– and [FeF6]3– is (Z=26).

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By Expert Faculty of Sri Chaitanya
a
both are paramagnetic
b
both are diamagnetic
c
[Fe(CN)6]3– is diamagnetic, [FeF6]3– is paramagnetic
d
[Fe(CN)6]3– is paramagnetic, [FeF6]3– is diamagnetic

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detailed solution

Correct option is A

In both the complexes the central metal ion is Fe+3In [Fe(CN)6]-3 the ligand is strong (CN-), rearrangement occursIn [FeF6]-3 the ligand is weak (F-) , no rearrangement.


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