The correct statement regarding the basicity of arylamines is

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arylamines are generally more basic than alkylamines because of aryl group

arylamines are generally more basic than alkylamines, because the nitrogen atom in arylamines is sp-hybridised

arylamines are generally less basic than alkylamines because the nitrogen lone-pair electrons are delocalised by interaction with the aromatic ring π-electron system

arylamines are generally more basic than alkylamines because the nitrogen lone-pair electrons are not delocalised by interaction with the aromatic ring π -electron system.

answer is C.

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Detailed Solution

In arylamines, lone pair of electrons on nitrogen atom is delocalised over the benzene ring, thus, not available for donation. So, arylamines are less basic than alkylamines R-N¨H2

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