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Q.

The correct statement (s) about surface properties is (are)

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a

Adsorption is accompanied by decrease in enthalpy and decrease in entropy  of the system

b

Cloud is an emulsion type of colloid in which liquid is dispersed phase and gas is dispersion medium

c

The critical temperatures of ethane and nitrogen are 563K and 126K ,respectively. The adsorption of ethane will be more than that of nitrogen on same amount of activated charcoal at a given temperature

d

Brownian motion of colloidal particles does not depend on the size of the particles but depends on viscosity of the solution

answer is A.

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Detailed Solution

Adsorption degree of freedomDecreases so DS = NegativeΔG=−ve( Spon tan eous )ΔS=−veΔH=−veΔG=ΔH−TΔS =−ve−T(−ve)At low temp. favoursCloud is not emulsionxmαTc  as  Tc (critical temp ↑ High liquification ↑ all reactions ↑xm also ↑ )
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