CrH2O6Cl3 has a magnetic moment of 3.83 B.M. According to CFT, the correct distribution of 3d electrons in the chromium ion of complex is
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a
3dxy1 , 3dyz 1, 3dz21
b
3dx2-y21 , 3dz21 , 3d zx1
c
3d zx1 ,3dx2-y21 , 3dyz1
d
3d xy1 ,3dyz1 , 3dzx1
answer is D.
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Detailed Solution
Cr=Ar4s13d5; Cr+3=Ar3d3;t2g set of orbitals are dxy, dyz, dxz;According to CFT configuration is t2g3 eg0; Thus the distribution is 3d xy1 ,3dyz1 , 3dzx1;