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Q.

CrH2O6Cl3 has a magnetic moment of 3.83 B.M.  According to CFT, the correct distribution of 3d electrons in the chromium ion  of complex is

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a

3dxy1 , 3dyz 1,  3dz21

b

3dx2-y21 ,   3dz21 , 3d zx1

c

3d zx1 ,3dx2-y21 ,   3dyz1

d

3d xy1 ,3dyz1 ,   3dzx1

answer is D.

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Detailed Solution

Cr=Ar4s13d5; Cr+3=Ar3d3;t2g set of orbitals are dxy, dyz, dxz;According to CFT configuration is t2g3 eg0; Thus the distribution is 3d xy1 ,3dyz1 ,   3dzx1;
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CrH2O6Cl3 has a magnetic moment of 3.83 B.M.  According to CFT, the correct distribution of 3d electrons in the chromium ion  of complex is