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Q.

CrH2O6Cl3 (at no. of Cr = 24) has a magnetic moment of 3.83 B.M. The correct distribution of 3d electrons in the chromium of the complex

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a

3dxy1,  3dyz1,  3xz1

b

3dxy1,  3dyz1,  3d 1z2

c

3dx2−y21,  3d  z21,  3d 1xz

d

3d  xy1, 3dx2−y21 3dyz1

answer is A.

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Detailed Solution

Cr3+ = 1s2 2s2 2p6, 3s23p63d3.  The    3d  xy1  3dxz1 3dyz1  has  lower  energy
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