Q.
The decomposition of A follows two parallel first order reactions, with K1=1.26×10-4& K2=3.8×10-5 are shown bellow. The percentage distribution of B and C are
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a
90 % B and 10%C
b
80% B and 20%C
c
60% B and 40%C
d
76.83 of B and 23.17% C
answer is D.
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Detailed Solution
For two parallel reactionskaverage=k1+k2 = 1.26×10−4+3.8× 10−5 =1.64× 10−4sec−1The fractional yield of B=kBkav=1.26×10−41.64×10−40.7683⇒76.83%The fractional yield of C=kBkav=0.38×10−41.64×10−4=0.2317⇒23.17%
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