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Q.

The decomposition of N2O4  to  NO2 is carried out at 280 K in chloroform. When equilibrium has been established, 0.2 mol of N2O4  and 2 × 10-3  mol of  NO2 are present in 2 litre solution. The equilibrium constant for reaction N2O4  ⇌  2NO2 is

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a

1 × 10-2

b

2 × 10-3

c

1 × 10-5

d

2 × 10-5

answer is C.

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Detailed Solution

K=NO22N2O4 = 2 × 10-32222 = 10-610-1=10-5
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The decomposition of N2O4  to  NO2 is carried out at 280 K in chloroform. When equilibrium has been established, 0.2 mol of N2O4  and 2 × 10-3  mol of  NO2 are present in 2 litre solution. The equilibrium constant for reaction N2O4  ⇌  2NO2 is