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Q.

In the decomposition of solid metallic carbonate  MCO3 into solid metal oxide and carbon dioxide gas, the partial pressure is increases by 10 times when temperature changes from 400 K to 500 K. The average value of enthalpy change (ΔH) for the reaction in the given temperature range in kcal/ mole is ____? take R=2cal.K-1.mole-1

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answer is 9.21.

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Detailed Solution

MCO3(s)⇌MO(s)+CO2(g vont Hoff equation   KP=PCO2logKP2KP1=ΔH2.303R1T1-1T2log10=ΔH2.303×2cal100200000ΔH=9.212kcal.mole-1
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