Q.

The decreasing order of reactivity of the following compounds towards nucleophilic substitution (SN2) is:

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a

(IV) > (II) > (III) > (I)

b

(II) > (III) > (IV) > (I)

c

(II) > (III) > (I) > (IV)

d

(III) > (II) > (IV) > (I)

answer is B.

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Detailed Solution

Electron with drawing group increases the rate of SN2 reactionNet electron withdrawing will be maximum in (II) as – NO2 is closer w.r.t III.In (IV) only –I of – NO2 will be applicable as it is present on meta position
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