Q.
Dimethyl ether decomposes as CH3OCH3(g)⟶CH4(g)+CO(g)+H2(g) When CH3OCH3, decomposes to 20% extent at certain fixed conditions, what is the ratio of diffusion of pure CH3OCH3 with methane?
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a
0.59 : 1
b
1.18 : 1
c
2.36 : 7
d
1.77 :7
answer is C.
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Detailed Solution
CH3OCH3(g)→CH4(g)+CO(g)+H2(g) Initial press.: 1 0 at euilibrium: 1-x x 1-0.2 0.2 ∵x=20% = 0.2rCH3OCH3rCH4=MCH4MCH3OCH3×PCH3OCH3PCH4=1646×0.80.2=2.36:1
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