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Q.

Dipole moments of four methyl halides is 1.636D, 1.847D, 1.83D, 1.86D. Methyl fluoride has a dipole moment of

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a

1.86 D

b

1.847 D

c

1.83 D

d

1.636 D

answer is B.

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Detailed Solution

Expected dipole moment based on C - X polarityCH3F>CH3Cl>CH3Br>CH3IBut Î¼=e×dcumulative effect of bond polarity and C - X bond length is maximum for CH3Cl.C−Cl bond is much longer than C - F bond∴ Experimentally Î¼ for CH3Cl1.86D>CH3F1.847D>CH3Br1.83D>CH3I1.636D
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