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Q.

In the disproportionation reaction, 3HClO3 →HClO4 + Cl2 + 2O2 + H2O, the equivalent mass of the oxidising agent is (molar mass of HClO3 = 84.45)

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Detailed Solution

It is a disproportion reaction. HClO3 acts like both oxidant and reductantEW of HClO3 as oxidization agentDecrease in O state = 5EW of HClO3 as an oxidant =84.455= 16.89
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In the disproportionation reaction, 3HClO3 →HClO4 + Cl2 + 2O2 + H2O, the equivalent mass of the oxidising agent is (molar mass of HClO3 = 84.45)