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Q.

On dissolving 0.5 g of a non-volatile non-ionic solute to 39 g of benzene, its vapor pressure decreases from 650 mm Hg to 640 mm Hg. The depression of freezing point of Benzene (in K) upon addition of the solute is_____(Given data : Molar mass and the molal freezing point depression constant of benzene are 78 g mol-1 and 5.12 K.kg  mol-1, respectively)

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answer is 1.03.

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Detailed Solution

10650=nBnA+nB               nB=10 nA=640                           m=10×1000640×78 Δtf=5.12×10×1000640×78=1.025≃1.03
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