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Q.

During change of O2 to O2- ion, the electron adds on which one of the following orbitals

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a

π∗ orbital

b

π orbital

c

σ′ orbital

d

σ orbital

answer is A.

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Detailed Solution

O2⟶+1e−O2−Molecular orbital configuration of O2 σ1s2σ∗1s2σ2s2σ∗2s2σ2pz2π2px2=π2py2π∗2px1=π∗2py1therefore incoming  e− would enter into  π∗2pxmolecular orbital
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During change of O2 to O2- ion, the electron adds on which one of the following orbitals