Q.
During the free redical chlorination of methane, which of the following reactions has the lowest collision frequency?
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a
Cl∙+∙CH3→CH3Cl
b
Cl∙+Cl2→Cl2+Cl∙
c
∙CH3+CH4→CH4+∙CH3
d
∙CH3+Cl2→CH3Cl+Cl∙
answer is A.
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Detailed Solution
In (1), it is terminating step, therefore it have less chance of collision.
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