During the free redical chlorination of methane, which of the following reactions has the lowest collision frequency?

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Cl∙+∙CH3→CH3Cl

Cl∙+Cl2→Cl2+Cl∙

∙CH3+CH4→CH4+∙CH3

∙CH3+Cl2→CH3Cl+Cl∙

answer is A.

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Detailed Solution

In (1), it is terminating step, therefore it have less chance of collision.

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