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Q.

EAN of the central metal atom,/ion are equal in :

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a

∗(Ni(CO)]4,Fe(CN)64−

b

Ni(en)22+,FeH2O62+

c

Co(CN)63−,Fe(CN)63−

d

Ni(en)22+,FeH2O63+

answer is A.

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Detailed Solution

[Ni(CO)]4EAN =28-0 +2x4 =28+8 =36Fe(CN)64−EAN = 26 -2 +6x2 =26 -2 +12 =36
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EAN of the central metal atom,/ion are equal in :