An electric discharge is passed through a mixture containing 50 c.c. of O2 and 50 c.c. of H2. The volume of the gases formed (i) at room temperature and (ii) at 1100C will be
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a
(i) 25 c.c. (ii) 50 c.c.
b
(i) 50 c.c. (ii) 75 c.c.
c
(i) 25 c.c. (ii) 75 c.c.
d
(i) 75 c.c. (ii) 75 c.c.
answer is C.
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Detailed Solution
(i)At room temperature 2H2g + O2g → 2H2Ol 2moles 1mole 2moles 2×22.4l 22.4l 50ml ?(=25ml) given volume of O2=50 ml volume of O2 released(which is unreacted)=50-25 =25ml volume of gases formed at room temperature = 25cc(since H2O formed is liquid)(ii) At 110°c : 2H2g + O2g → 2H2Og 50ml 25ml 50ml volume of gases formed =volume of H2O(g) formed+volume of O2 unreacted = 50 + 25 =75ml