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Q.

An electric discharge is passed through a mixture containing 50 c.c. of O2 and 50 c.c. of H2. The volume of the gases formed (i) at room temperature and (ii) at 1100C will be

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a

(i) 25 c.c. (ii) 50 c.c.

b

(i) 50 c.c. (ii) 75 c.c.

c

(i) 25 c.c. (ii) 75 c.c.

d

(i) 75 c.c. (ii) 75 c.c.

answer is C.

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Detailed Solution

(i)At room  temperature  2H2g +  O2g  →  2H2Ol                                  2moles     1mole     2moles                                   2×22.4l     22.4l                                      50ml         ?(=25ml) given volume of O2=50 ml volume of O2 released(which is unreacted)=50-25 =25ml volume of gases formed at room temperature = 25cc(since H2O formed is liquid)(ii) At 110°c :                      2H2g +  O2g  →  2H2Og                     50ml      25ml       50ml volume of gases formed =volume of H2O(g) formed+volume of O2 unreacted                                       = 50 + 25 =75ml
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