Banner 0
Banner 1
Banner 2
Banner 3
Banner 4
Banner 5
Banner 6
Banner 7
Banner 8
Banner 9

Q.

In the electrolysis of aqueous sodium chloride solution which of the half-cell reaction will occur at anode?

see full answer

High-Paying Jobs That Even AI Can’t Replace — Through JEE/NEET

🎯 Hear from the experts why preparing for JEE/NEET today sets you up for future-proof, high-income careers tomorrow.
An Intiative by Sri Chaitanya

a

Na+(aq)+e−⟶Na(s);Ecell∘=−2.71V

b

2H2O(l)⟶O2(g)+4H+(aq)+4e−;Ecell∘−1.23V

c

H+(aq)+e−⟶12H2(g);Ecell∘=0.00V

d

Cl−(aq)⟶12Cl2(g)+e−;Ecell ∘=1.36V

answer is D.

(Unlock A.I Detailed Solution for FREE)

Best Courses for You

JEE

JEE

NEET

NEET

Foundation JEE

Foundation JEE

Foundation NEET

Foundation NEET

CBSE

CBSE

Detailed Solution

In case of electrolysis of aq .NaCl oxidation reaction occurs at anode as follows:                        Cl−(aq)⟶12Cl2(g)+e−;E∘=1⋅36V2H2O(l)⟶O2(g)+4H+(aq)+4e−⋯; Ecell∘=1.23VBut due to lower Ecello value, water should get oxidised in preference of Cl- (aq)However, the actual reaction taking place is the first one i.e. Cl2 is produced.This unexpected result is explained on the basis of the concept of 'over voltage', i.e. water needs greater voltage for oxidation to O2 (as it is kinetically slow process) than that needed for oxidation of Cl- ions to Cl2.
Watch 3-min video & get full concept clarity

courses

No courses found

score_test_img

Get Expert Academic Guidance – Connect with a Counselor Today!

whats app icon