An electrolytic cell is constructed for preparing hydrogen. For an average current of 1 ampere in the circuit, the time required to produce 450 mL of hydrogen at NTP is approximately.
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a
30 min
b
1 hour
c
2 hours
d
5 hours
answer is B.
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Detailed Solution
22,400 ml H2 at STP = 1 mol H2∴ 450 mL H2 at STP =450 mL22,400 mL×1 mole H2=0.02 molElectrode reaction: 2H++2e−→H22 F 1 molSo, the liberation of 0.02 mole of H2 requires =2×96,500×0.02C=3860 CTime required to produce 0.02 mole t =QI=3,8601=1.07 h≈1 hour