Q.

For the electrolytic production of NaClO4 from NaClO3 according to the equation NaClO3+H2O→NaClO4+H2 the number of Faradays of electricity required to produce 0.5 mole of NaClO4 is

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a

1

b

2

c

3

d

1.5

answer is A.

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Detailed Solution

Change in oxidation state = 7 - 5 = 2To produce 1 mole of NaClO4 = 2 F requiredTo produce 0.5 mole of NaClO4 = 0.5 x 2 = 1 F
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For the electrolytic production of NaClO4 from NaClO3 according to the equation NaClO3+H2O→NaClO4+H2 the number of Faradays of electricity required to produce 0.5 mole of NaClO4 is