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Q.

Electron affinity is maximum for :

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a

Cl

b

F

c

Br

d

I

answer is A.

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Detailed Solution

Generally, electron affinity decreases down the group and increases in a period. However the electron affinity of Cl is more than F because of the smaller size of F due to which there is a greater repulsion between the incoming electron and electrons present in valence shell of F-atom. Hence, Cl has the maximum electron affinity among halogens.
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Electron affinity is maximum for :