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The electronic spectrum of shows a single broad peak with a maximum at . The crystal field stabilization energy (CFSE) of the complex ion, in kJ , is :
detailed solution
Correct option is D
complex TiH2O6+3 gives a peak at 20,300 Gm−1The crystal field strabilization energy is Δ0=hcr¯∴Δ0=6.625×10-34×3×108×20,300=4×10-19 J/ molecule =6.023×1023×4×10-19 J/mole=243005 J/mole=243 kJ/mole∣Ti-22[Ar]4s23d2Ti+3-[Ar]4s°3d1 CFSE=0.4Δ0=0.4×243 kJ/mole=97 kJ/moleTalk to our academic expert!
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Simplified absorption spectra of three complexes ((i), (ii) and (iii)) of ion are provided below; their values are marked as A, B and C respectively. The correct match between the complexes and their values is:
(i) (ii) (iii)
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