Q.
The electronic spectrum of TiH2O63+ shows a single broad peak with a maximum at 20,300 cm−1 . The crystal field stabilization energy (CFSE) of the complex ion, in kJ mol−1, is : 1 kJ mol−1=83.7 cm−1
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a
242.5
b
83.7
c
145.5
d
97
answer is D.
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Detailed Solution
complex TiH2O6+3 gives a peak at 20,300 Gm−1The crystal field strabilization energy is Δ0=hcr¯∴Δ0=6.625×10-34×3×108×20,300=4×10-19 J/ molecule =6.023×1023×4×10-19 J/mole=243005 J/mole=243 kJ/mole∣Ti-22[Ar]4s23d2Ti+3-[Ar]4s°3d1 CFSE=0.4Δ0=0.4×243 kJ/mole=97 kJ/mole
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