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Q.

An endothermic reaction is non-spontaneous at freezing point of water and becomes feasible at its boiling point, then:

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a

ΔH=−ve,ΔS=+ve

b

Both ΔH and ΔS are + ve

c

Both ΔH and ΔS are -ve

d

ΔH=+ve,ΔS=−ve

answer is B.

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Detailed Solution

ΔG=ΔH−TΔS At low T,ΔH, and ΔS are + ve but ΔG is also + ve  At high temperature TΔS>ΔH and ΔG=−ve
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