Q.

The enthalpy changes states for the following processes are listed belowCl2g = 2Cl(g);                     242.3 kJ mol-1 I2g = 2I(g);                           151.0 kJ mol-1 IClg = I(g)+Cl(g);               211.3 kJ mol-1 I2s = I2(g);                             62.76 kJ mol-1 Given that the standard states for iodine chlorine are I2s  and  Cl2g, the standard enthalpy of formation for ICl (g) is

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a

+ 244.8 kJ mol-1

b

- 14.6 kJ mol-1

c

- 16.8 kJ mol-1

d

+ 16.8 kJ mol-1

answer is D.

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Detailed Solution

I2+Cl2→2ICl ∆H=eI2S→g + eI-I +eCl-Cl -2 × eI-Cl  =62.76+151.0+242.3 - 2 × 211.3 =33.46 kJ for 2 moles of ICl ∴  ∆H/mol = 33.462=16.73 kJ mol-1
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