Q.

Equal volumes of three acid solutions of pH 3, 4 and 5 are mixed in a vessel. What will be the H+ ion concentration in the mixture ?

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a

3.7× 10-3 M

b

1.11× 10-3 M

c

1.11× 10-4 M

d

3.7× 10-4 M

answer is D.

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Detailed Solution

Let volume of each solution taken is 1 litH+1 = 10-3 M,  H+2 = 10-4 M ,   H+3 = 10-5 M  for the given acids.Mmix Vmix = M1V1 + M2V2 + M3V3 Mmix × 3 = [10-3 × 1]+[10-4 × 1]+[10-5× 1] Mmix=10-5100+10+13 = 111 ×10-5 3 =37 × 10-5 M =3.7 × 10-4M
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