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Q.

The equilibrium constant for the reaction  N2(g)+O2(g)⇌2NO(g) is 4×10-4 at 2OOK. In presence of a catalyst, equilibrium is attained ten times faster. Therefore, the equilibrium constant in presence of the catalyst at 200 K is :

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a

40×10-4

b

4×10-4

c

4×10-3

d

difficult to compute without more data

answer is B.

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Detailed Solution

Equilibrium constant is only temperature dependant.
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The equilibrium constant for the reaction  N2(g)+O2(g)⇌2NO(g) is 4×10-4 at 2OOK. In presence of a catalyst, equilibrium is attained ten times faster. Therefore, the equilibrium constant in presence of the catalyst at 200 K is :