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Equilibrium constants of following reactions given asS(s)+O2(g)⇌SO2(g);K12S(s)+3O2(g)⇌2SO3(g);K22SO3(g)⇌2SO2(g)+O2(g);K3Correct relation between the equilibrium constants at same temperature is ___?

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a

K3=2K1+K2

b

K2=2K1+K3

c

K3=2K1·K2

d

K2=K21K3

answer is D.

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Detailed Solution

According to law of mass actionK1=SO2O2K2=SO32O23K3=SO22O2SO32

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Equilibrium constants of following reactions given asS(s)+O2(g)⇌SO2(g);K12S(s)+3O2(g)⇌2SO3(g);K22SO3(g)⇌2SO2(g)+O2(g);K3Correct relation between the equilibrium constants at same temperature is ___?