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Q.

The equilibrium P4(g)+6Cl2(g)⇌4PCl3(g)  is attained by mixing equal number of moles of reactants, then at equilibrium

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a

[Cl2]>[PCl3]

b

[Cl2]>[P4]

c

[P4]>[Cl2]

d

[PCl3]>[P4]

answer is C.

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Detailed Solution

P4+6Cl2⇌4PCl3     1           1                 0          x          6x             4x     _ (1−x)  (1−6x)      4x            ⇒[P4]>[Cl2]
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The equilibrium P4(g)+6Cl2(g)⇌4PCl3(g)  is attained by mixing equal number of moles of reactants, then at equilibrium