Q.

For the equilibrium reaction PCl5(g) ⇌PCl3(g) + Cl2(g) ; Kc at 360 K is 0.01 mole/lit. Kp for the same reaction at same temperature is

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a

3 atm

b

30 atm

c

0.03 atm

d

0.3 atm

answer is D.

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Detailed Solution

Kp = KcRT∆ng∆ng=1Kp = 10-2112×360= 0.3 atm
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For the equilibrium reaction PCl5(g) ⇌PCl3(g) + Cl2(g) ; Kc at 360 K is 0.01 mole/lit. Kp for the same reaction at same temperature is