Q.

The equivalent conductance of NaCl at concentration C and at infinite dilution are λC and λ∞ respectively The correct relationship between λC and λ∞ is given as (where, the constant B is positive)

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a

λC=λ∞+(B)C

b

λC=λ∞−(B)C

c

λC=λ∞−(B)C

d

λC=λ∞+(B)C

answer is C.

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Detailed Solution

According to Debye Huckel Onsager equation,           λC=λ∞−BCwhere, λC = limiting equivalent conductivity at concentration C          λ∞  = limiting equivalent conductivity at infinite dilution              C = concentration
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