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Q.

Ethyl acetate reacts with CH3MgBr to form

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a

Secondary alcohol

b

Tertiary alcohol

c

Primary alcohol and an acid

d

An acid

answer is B.

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Detailed Solution

Esters react with Grignard reagent to form tert -alcohols having at least two alkyl groups, introduced through Grignard reagent, identical, the third introduced through ester may be similar or different. CH3COOC2H5+CH3Mgl→H2OCH3COCH3        →(ii) H2O(i) CH3MglCH3−C|OH|CH2CH3−CH3
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Ethyl acetate reacts with CH3MgBr to form