Q.
Every o – substituted aniline, whether the substituent is electron- donating (or) electron withdrawing is
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a
Less basic than aniline
b
More basic than aniline
c
Equal to basic nature of aniline
d
None
answer is A.
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Detailed Solution
The electron – donating group increases and electron – withdrawing group decreases the basic strength of amines but ortho substituted aniline irrespective of EDG/EWG is less basic than aniline. this is known as ortho effect
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