Q.

Every o – substituted aniline, whether the substituent is electron- donating (or) electron withdrawing is

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a

Less basic than aniline

b

More basic than aniline

c

Equal to basic nature of aniline

d

None

answer is A.

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Detailed Solution

The electron – donating group increases and electron – withdrawing group decreases the basic strength of amines but ortho substituted aniline irrespective of EDG/EWG is less basic than aniline. this is known as ortho effect
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Every o – substituted aniline, whether the substituent is electron- donating (or) electron withdrawing is