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a
Hydrolysis of ester in acidic medium
b
Formation of nitric oxide from its elements
c
Decomposition of ammonium carbamate
d
Reaction of barium chloride and potassium sulphate
answer is D.
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Detailed Solution
This is an example of precipitation reaction.BaSO4 ppt cannot react with KCl under the same experimental conditions under which BaCl2 (aq) and K2SO4 (aq) react with each other.