Q.

The examples of minimum boiling azeotropes are

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a

ethanol + acetone

b

carbon disulphide + acetone

c

ethanol + water

d

water+HNO3

answer is A.

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Detailed Solution

Mixtures of ethanol and acetone, carbon disulphide and acetone, ethanol and water show positive deviation from Raoult's law and thus, form minimum boiling azeotrope.
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The examples of minimum boiling azeotropes are