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The exothermic formation of ClF3 is represented by the equation :Cl2 + 3F2(g) ⇌ 2ClF3(g); ∆H = -329 kJWhich of the following will increase the quantity of ClF3 in an equilibrium mixture ofCl2, F2 and ClF3 ?

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a

Increasing the temperature

b

Removing Cl2

c

Increasing the volume of container

d

Adding F2

answer is D.

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Detailed Solution

Favourable conditions for forward reaction according to Le-Chatelier principal are : (a) Decrease in temperature (b) Increase in concentration of reactant and (c) Increase in pressure.

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The exothermic formation of ClF3 is represented by the equation :Cl2 + 3F2(g) ⇌ 2ClF3(g); ∆H = -329 kJWhich of the following will increase the quantity of ClF3 in an equilibrium mixture ofCl2, F2 and ClF3 ?