In a face centred cubic lattice, atom A occupies the corner positions and atom B occupies face centre positions, if one atom of B is missing from one of the face centred points, the formula of the compounds is A2Bx the value of x is :
Number of effective A atoms
= 8 corners × 1/8 per corner atom share
= 1 atom / unit cell
Number of atoms on faces of a cube = 6 atoms
If one is missing from one face, number of atoms left = 5
× ½ per face atom share =per unit cell
The formula of the compound is AB5/2.
On simplify we get, the formula A2B5.