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Q.

False statement  among  the following is

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a

In oxoanions of Cr and Mn (CrO4−2,Cr2O7-2 ,MnO4− ,MnO4−2) the pi bond formation involves overlap of d-orbital of transition metal and p-orbital of oxygen

b

Colour of Permanganate, Chromate and dichromate is due to charge transfer from LLigand → M(Metal)

c

The starting material to prepare K2Cr2O7 is Chromite ore(FeO.Cr2O3)

d

K2Cr2O7 is more soluble  in water than Na2Cr2O7

answer is D.

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Detailed Solution

Na2Cr2O7 is highly soluble in water. It is deliquescent and exists as crystalline Na2Cr2O7­. 2H2O
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