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False statement among the following is 

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a
Formaldehyde is soluble in water
b
Acetic acid exists as dimer in benzene
c
Acetone is a pleasant smelling liquid
d
Acetaldehyde is insoluble in water

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detailed solution

Correct option is D

HCHO, CH3CHO, CH3COCH3 are soluble in waterLower aldehydes & Ketones are soluble in water due to Polar nature.Ketones are pleasant smellingLower aldehydes are pungent smelling but as molecular weight increases  their odour becomes  pleasant.

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Statement 1: Lower aldehydes and ketones are soluble in water but the solubility decreases as the molecular mass increases.

Statement 2: Reaction with HCN is used to distinguish  between aldehydes and ketones


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