In a F.c.c arrangement of A and B atoms, where A atoms are at the corners of the unit cell, B atoms at the face centers, two atoms are missing from two corners in each unit cell, then the simplest formula of the compound is
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a
A7B6
b
A6B7
c
A7B24
d
AB4
answer is D.
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Detailed Solution
Since there are six atoms (A) at the corner of the unit cell. So, contribution of atoms in 1 unit cell is 68.Since 3 face-centered atoms (B) contributes to one unit cell So, formula is A6/8B3or A6B24, or AB4