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Q.

In a F.c.c arrangement of A and B atoms, where A atoms are at the corners of the unit cell, B atoms at the face centers, two atoms are missing from two corners in each unit cell, then the simplest formula of the compound is

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a

A7B6

b

A6B7

c

A7B24

d

AB4

answer is D.

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Detailed Solution

Since there are six atoms (A) at the corner of the unit cell. So, contribution of atoms in 1 unit cell is 68.Since 3 face-centered atoms (B) contributes to one unit cell So, formula is A6/8B3or A6B24, or AB4
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