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Find the correct increasing order of acidic strengths(A) ClCH2COOH(B) CH(Cl2)COOH(C) CCl3COOH(D) HCOOH

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a

A > B > C > D

b

D > B > C > A

c

C > D > A > B

d

C > B > A > D

answer is D.

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Detailed Solution

It is due to the negative inductive effect of chlorine atoms, which lowers the electron density of the C atoms from - position to the carboxylic group that leads to the more stabilization of conjugate base or In simple words greater the -I effect greater the acidity.

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