Q.

Find out wrong statement for an octahedral complex.

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a

Central metal cation with d6 configuration is diamagnetic in strong ligand field.

b

Central metal cation with d5 configuration has one unpaired electron in both weak and strong ligand field.

c

Central metal cation with d8 configuration has two unpaired electrons in weak, strong and also in mixed ligand field.

d

Central metal cation with d4 ,d5, d6 and d7 configuration have different number of unpaired electrons in weak and strong ligand field.

answer is B.

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Detailed Solution

Central metal cation with d5 configuration has the unpaired electron in strong ligand field and 5 (five) unpaired electrons in weak ligand field.
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