Q.
Find the pH of solution prepared by mixing 25 ml of a 0.5 M solution of HCl, 10 ml of a 0.5 M solution of NaOH and 15 ml of water
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a
0.8239
b
1.0029
c
1.0239
d
1.8239
answer is A.
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Detailed Solution
We know that HCl and NaOH reaction is neutralization,( m.e. = milli-equivalent)∴ m.e. of HCl = 0.5 × 25=12.5 m.e. of NaOH = 0.5 × 10=5.0m.e. of HCl in the resultant mixture= 12.5 - 5.0 = 7.5Total volume = (25 + 10 + 15) ml = 50 ml∴ Normality of HCl = m.e.Vol(ml)=7.5050 ∴ Molarity = 7.5050 ∴ H+ = 7.5050 ∴ pH = -log 7.5050 = 0.8239
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