The first (IE1) and second (IE2) ionisation enthalpies (kJ/mole) of element, A are given below. AIE1 750IE2 1500In an experiment 1/12 mole of A atom in vapour phase absorb 100 kJ of energy. So that it forms a mixture of A+ and A2+ ions. Energy utilized to form A2+ from A+ in experiment is
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a
1500 kJ
b
750 kJ
c
62.5 kJ
d
37.5 kJ
answer is D.
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Detailed Solution
Energy required to convert A to A+=112 × 750=62.5 kJRemaining energy to convert A+ to A2+ =100−62.5 =37.5 kJ.